Over 1001 skill the main factor with succesfull overcharging is the quality of the gems.
On a 5.5 point overcharge i always use 2x99% and 2x98% and ive never had a blow up yet (touch wood cos im doing a full set of 5 point OC in 10 minutes )
Also if your only putting 3 gems onto an item , bear in mind that the empty slot is classed as a 94% gem so has a greater chance of blowing up.
You also dont have to have 2x99 and 2x98 , you could have say 3x99 and 1x97 , aslong as the quality of all 4 gems add up to 394 (as in 99+99+98+98=394) you should be fine.
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